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The development of more robust, sensitive photodetector materials, microelectromechanical systems (MEMSs), and ber optics and the perpetual advancement of computing power (as predicted by Moore s law) have both increased the performance and reduced the cost of PAC As a result, PAC is now a critical part of routine operations within the realm of industrial chemistry Many general reviews on the subject of PAC (and PAT) have been published [6 10] A series of literature reviews on the subject of PAC have been published regularly in Analytical Chemistry The rst review [11] listed manuscripts published between 1987 and 1992, covering seven speci c topics (general PAC, chromatography, optical spectroscopy, ber optics, mass spectrometry, chemometrics, and ow injection analysis), along with a section on needs for the future of PAC; in all, the rst review included 507 references.

3. To use the file, go to the Customize tab and choose Main CUI File from the drop-down list in the Customizations In pane. Then click the Load Partial Customization File button to the right of the drop-down list. In the Open dialog box, locate the partial CUI file and click Open. 4. Choose Main CUI File again from the drop-down list. You should now see the new file listed under the expanded Partial CUI Files item. You can load more than one partial customization file along with the main customization file. For example, you might have one partial customization file for 2D work and another for 3D work; sometimes, you might want both of them. You can load and unload partial customization files in two ways: Use the CUILOAD command as explained in the previous section. Use the CUI command to open the Customize User Interface dialog box. To load a file, click the Load Partial Customization File button in the Customizations In pane. Select the file and click Open. In the Customize User Interface dialog box, click Apply.

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Chem Soc, 1996, 118, 1002 1005 6 1 A recent study (Seeman, J I; Grassian, V H; Bernstein, E R, J Am Chem Soc, 1988, 110, 8542) has demonstrated that -methylstyrene is nonplanar in the ground state but is planar in its rst excited state This may be interpreted as evidence that the p bond order of the bond connecting the vinyl group to the ring is greater in the lowest p p state than in the ground state Can you o er an explanation for this observation by considering the properties of styrene to arise from the interaction of a benzene ring with ethylene Answer The HOMOs and LUMOs of benzene and ethylene have the same SHMO energies, j j and j j, respectively These HOMOs interact, the out-of-phase combination becoming the HOMO of styrene.

re ections are unwanted, and over the last 15 years methods based on separating these different interferograms in the data processing stage have been developed so as to avoid immersing the sample in oil or coating the surfaces with an index-matching lacquer (Okada et al., 1990; Deck, 2003; de Groot, 2000; Burke et al., 2006; Hibino et al., 2003; Hibino et al., 2004; Hibino and Takatsuji, 2002). However, these techniques could not be applied to measure thicknesses down to a few microns. Measurement of transparent layers of a few microns in thickness is often laid on

Subsequent reviews were published in 1995 [12], 1999 [13], 2001 [14], 2003 [15], and 2005 [16] The review series is an essential resource for scientists seeking information on speci c PAC methods; in total, 2650 references covering more than 16 topics were catalogued by the authors Currently there are three major consortia involving university, government, and industrial partners CPAC, the Measurement & Control Engineering Center (MCEC), and the Control Theory and Applications Centre (CTAC) along with an annual conference, the International Forum on Process Analytical Chemistry (IFPAC), and numerous online resources that are devoted to issues related to process analytics [16] In parallel with the FDA s initiative, the term process.

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Thus the HOMO of styrene is antibonding across the bond connecting the vinyl group to the ring Upon photoexcitation, one electron leaves this orbital, resulting in a net increase of the p bond order of this bond The LUMO of styrene corresponds to the in-phase combination of the LUMOs of ethylene and benzene and therefore contributes a positive contribution to the p bond order of the connecting bond when it receives the photoexcited electron..

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